Preparation of chiral α-substituted alaninates through an efficient diastereoselective synthesis of trisubstituted allylic alcohols

Keyphrases

• Trisubstituted 100%
• Allylic Alcohols 100%
• Diastereoselective Synthesis 100%
• In Situ 50%
• Alkynes 50%
• Zirconia 50%
• Carboalumination 50%
• Diastereoselective Addition 50%
• Highly Diastereoselective 50%
• 6-dimethyl-1 50%
• 1,4-Dioxane 50%
• Carbaldehyde 50%
• Overman 50%
• Allylic Amines 50%
• Chiral Quaternary Carbon Stereocenters 50%

Chemistry

• Alaninate 100%
• Allylic Alcohol 100%
• Alkyne 50%
• 1,4-dioxane 50%
• Zirconium 50%
• Overman Rearrangement 50%